Stylolites in twelve stratigraphic sections of the Salem Limestone, distributed throughout the Illinois Basin, provide clues to their origin and development. Chemical and X-ray diffraction analyses reveal that stylolite seam material contains organic matter and clay minerals too sparse or absent in the host limestone to be considered solely as insoluble residue. Stylolite distribution in various lithofacies suggests that stylolites develop along thin sedimentary layers rich in organic matter and clay minerals. Stylolite density (vertical distribution) mimics the distribution of organic-rich sedimentary layers: sparse but thick in grainstone, and abundant but thin in packstone and wackestone. Many stylolites grade laterally into organic-rich layers, or hummocky seams. Thicknesses of stylolite caps and hummocky seams are approximately equal in the same host rock, but hummocky seams tend to be more laterally continuous. Stylolite density in packstone increases with burial depth, whereas hummocky seam density decreases. Hummocky seam thickness does not change with depth. Stylolite column height in grainstone, which is sparse in hummocky seams, increases with depth, whereas stylolite density does not increase. This list of observations supports the hypothesis that stylolites develop along pre-existing, organic-rich layers, or hummocky seams, rather than nucleating in pure host rock and creating organic-rich seams as accumulations of insoluble residue. Volumetric calculations indicate that the contribution of stylolites to pore-filling cement is 5 to 25 percent throughout the Illinois Basin.
The depositional style, biostratigraphy and burial history of the Late Early Pliocene, Moruga Group were studied in outcrop and the subsurface, along the south coast of Trinidad to determine its depositional environments, sediment sources, geologic age, and diagenetic history.
Alkylammonium ion exchange, x-ray powder diffraction (XRD), x-ray fluorescence spectroscopy (XRF), and high resolution transmission electron microscopy (HRTEM) have been used to study the chemistry and the physical properties of illite/smectite (I/S) clays from Paleozoic K-bentonites. The data have been used to evaluate current models of I/S interstratification and the mechanism of formation of illite during bentonite diagenesis.
Rare occurences of coeval late Wisconsin glacigenic diamictons and ice-proximal sediments with a diverse faunal assemblage provided an opportunity to test the viability of the glacigenic sediments as proxy paleoclimate indicators.
In this dissertation I present a tectonic, geochemical, and thermal history for the Witwatersrand basin, located on the Archean Kaapvaal craton, South Africa. The foreland basin tectonic setting of the Central Rand Group controls both the chemical and the thermal evolution of the basin, and unifies the basin evolution model presented here.
Various geochemical parameters including type and abundance of organic matter (TOC), sulfide-sulfur quantities, fluctuations in bottom-water anoxicity (DOP), metal content differences, and sulfur isotope variations have been assessed in order to characterize Midcontinent Pennsylvanian black shales. Based on these geochemical parameters, the deposits can be grouped into three types: Mecca-type, Heebner-type, and Shanghai-type.
The Brassfield Formation is a very thin, highly condensed carbonate unit that encompasses most of the Llandovery (8.5 MMYR) and covers much of the eastern midcontinent. Fifty-six Brassfield outcrops exposed around the flanks of the Cincinnati arch comprise three members, four facies tracts, and seven lithofacies. The three types of condensation recognized in the Brassfield (dynamic bypass, punctuated deposition, and sediment starvation) are related to sea level fluctuations, manifested as a hierarchy of sequence orders, that ultimately controlled the spatial and temporal distribution of facies.
Little is known about the hydraulic fracturing of soil, although the technique holds potential for several environmental engineering applications. The dissertation research consists of laboratory experiments, where hydraulic fractures were created by injecting dyed glycerin into colluvium contained in a triaxial pressure cell, and a field test, where hydraulic fractures were created by injecting guar gum gel at shallow depths in glacial drift. The laboratory tests showed that hydraulic fractures are readily created in clayey-silt colluvium. Furthermore, hydraulic fractures created in soil with positive pore pressure were filled with two fluids: one injected to create the fracture, and pore fluid that infiltrates into the fracture tip. The length of the infiltrated tip increases with increasing fracture length.
Investigation of the coronal plates of the regular echinoid Strongy-locentrotus (Echinodermata: Echinoidea) shows that skeletal growth and chemistry may be interrelated.
The nature of taphonomic overprint affecting the fossil records of the regular echinoid Families Cidaridae, Diadematidae, Toxopneustidae and Echinometridae is investigated using a synthesis of actualistic and literature-derived data. The actualistic portion of this study focuses on the following extant members of the four families: Eucidaris tribuloides, Diadema antillarum, Tripneustes ventricosus and Echinometra lucunter. Population censuses of these animals in tropical reef and near-reef environments demonstrate that the distribution of macro- and microscopic skeletal material does not reflect the distribution of the living fauna. Field experiments with freshly-killed carcasses of Eucidaris, Diadema and Echinometra indicate that loss of all organic tissue occurs within six days after death, reducing these echinoids to essentially bleached carcasses.